Firefighters and rescue teams work at the Amuay oil refinery in Punto Fijo, Venezuela, Saturday, Aug. 25, 2012. A huge explosion rocked Venezuela's biggest oil refinery and unleashed a ferocious fire Saturday, killing over 20 people and injuring dozens in the deadliest disaster in memory for the country's key oil industry. (AP Photo/Diario EL Amanecer)
Firefighters and rescue teams work at the Amuay oil refinery in Punto Fijo, Venezuela, Saturday, Aug. 25, 2012. A huge explosion rocked Venezuela's biggest oil refinery and unleashed a ferocious fire Saturday, killing over 20 people and injuring dozens in the deadliest disaster in memory for the country's key oil industry. (AP Photo/Diario EL Amanecer)
A large fire rises over the Amuay refinery near Punto Fijo, Venezuela, Saturday, Aug. 25, 2012. A huge explosion rocked Venezuela's biggest oil refinery, killing at least 24 people and injuring dozens, an official said. (AP Photo/Ariana Cubillos)
PUNTO FIJO, Venezuela (AP) ? Venezuelans who live next to the country's biggest oil refinery said they smelled a strong odor of sulfur hours before a gas leak ignited in an explosion that killed at least 39 people and injured more than 80.
The Amuay refinery was still burning on Sunday more than a day after the blast, sending up a thick column of black smoke.
Residents in a neighborhood next to the refinery said that starting about 7 p.m. on Friday they noticed the unusually strong odor. Government officials say the blast occurred about 1:15 a.m. on Saturday when the gas leak created a cloud that ignited.
The cause of the disaster is under investigation.
Gabriela Nunez, a housewife who lives near the refinery, said she noticed the gas odor on Friday night and then hours later came the shock wave.
"All the windows shattered, the iron doors opened, the wooden doors broke," Nunez said. She returned to her home on Saturday night to gather belongings, saying she was worried about looters who had stolen goods from nearby stores hours after the explosion.
"That forced us to come back, even though we're afraid, to save what can be saved and secure our houses," Nunez said.
A total of 209 homes and 11 businesses were damaged in the explosion, and a National Guard post next to the refinery was destroyed, Vice President Elias Jaua said late Saturday. He said 18 of the victims were National Guard soldiers.
President Hugo Chavez on Saturday declared three days of mourning in the country.
Amuay is among the world's largest refineries and is part of the Paraguana Refinery Complex, which also includes the adjacent Cardon refinery. Together, the refineries process about 900,000 barrels of crude per day and 200,000 barrels of gasoline.
Oil Minister Rafael Ramirez said the country has enough fuel in storage, "10 days of inventories," to keep the Venezuelan market fully supplied with gasoline and diesel.
He said fires were still burning in two fuel storage tanks on Sunday but that other "process areas" of the refinery have been otherwise unaffected. Once the flames are completely extinguished, Ramirez said, "we have the ability to restart our refinery in two days."
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